364765-21-9Relevant articles and documents
Bifunctional phosphine ligand-enabled gold-catalyzed direct cycloisomerization of alkynyl ketones to 2,5-disubstituted furans
Hu, Xiaojun,Zhou, Bingwei,Jin, Hongwei,Liu, Yunkui,Zhang, Liming
supporting information, p. 7297 - 7300 (2020/07/14)
An efficient synthesis of 2,5-disubstituted furans directly from alkynyl ketones has been developed via tandem gold(i)-catalyzed isomerization of alkynyl ketones to allenyl ketones and cycloisomerization. The key to the success of this chemistry is the use of a biphenyl-2-ylphosphine ligand featuring a critical remote tertiary amino group.
Electrophilic carbocyclization of aryl propargylic alcohols: A facile synthesis of diiodinated carbocycles and heterocycles
Zhu, Hai-Tao,Ji, Ke-Gong,Yang, Fang,Wang, Li-Jing,Zhao, Shu-Chun,Ali, Shaukat,Liu, Xue-Yuan,Liang, Yong-Min
supporting information; experimental part, p. 684 - 687 (2011/05/03)
Diiodinated carbocycles and oxygen heterocycles can be readily synthesized by electrophilic carbocyclization of aryl propargylic alcohols in moderate to good yields under mild conditions. The resulting diiodide can be further exploited by subsequent oxidi