365-55-9

Basic information

• Product Name: Benzene,1,1'-thiobis[2-nitro-4-(trifluoromethyl)- (9CI)
• Synonyms: Sulfide,bis(a,a,a-trifluoro-2-nitro-p-tolyl) (6CI,8CI); NSC 39135
• CAS NO: 365-55-9
• Molecular Formula: C14H6 F6 N2 O4 S
• Molecular Weight: 412.2639
• Mol File: 365-55-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 391.4°Cat760mmHg
• Flash Point: 190.5°C
• Density: 1.64g/cm³
• CAS DataBase Reference: Benzene,1,1'-thiobis[2-nitro-4-(trifluoromethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1,1'-thiobis[2-nitro-4-(trifluoromethyl)- (9CI)(365-55-9)
• EPA Substance Registry System: Benzene,1,1'-thiobis[2-nitro-4-(trifluoromethyl)- (9CI)(365-55-9)

Safety Data

• Hazardous Substances Data: 365-55-9(Hazardous Substances Data)

Upstream product

• 121-17-5 2-chloro-3-nitro-5-trifluoromethylbenzene 
• 96-53-7 2-mercaptothiazoline 

Downstream Products

• 401-21-8 bis-(2-amino-4-trifluoromethyl-phenyl)-sulfide 
• 1598-28-3 bis-(2-nitro-4-trifluoromethyl-phenyl)-sulfoxide 
• 567-21-5 bis-(2-nitro-4-trifluoromethyl-phenyl)-sulfone 
• 382-81-0 bis-(2-amino-4-trifluoromethyl-phenyl)-sulfone 

Relevant articles and documents

-

-

STUDIES ON FLUORINE CONTAINING HETEROCYCLIC COMPOUNDS: 4. REACTIONS OF 3-NITRO-4-CHLOROBENZOTRIFLUORIDE AND 3,5-DINITRO-4-CHLOROBENZOTRIFLUORIDE WITH FIVE MEMBERED HETEROCYCLES

The reactions of 3-nitro-4-chlorobenzotrifluoride (1a) and 3,5-dinitro-4-chlorobenzotrifluoride (1b) with heterocycles (2-5) are described.Six S-linked and N-substituted heterocycles (6, 9-11, 13), such as 2-(2-nitro-4-trifluoromethylphenylthio)benzothiazole (9a), were prepared from the reactions of 1a with benzotriazole (2), 2-mercaptobenzothiazole (5a) and 2-mercaptobenzoxazole (5b) and from the reactions of 1b with 2, 1,2,4-triazole (3) and 5a in DMF respectively. 1a reacted with 2-mercaptothiazoline (4) to give the desired product 7 and bis(2-nitro-4-trifluoromethylphenyl) thioether (8). 3-(2-Benzoxazolyl)-2-benzoxazolinethione (15) was obtained from the reaction of 1b with 5b.The spectral data and elemental analyses were fully in accord with the proposed structures, and the possible mechanisms for these compounds and other by-products were discussed.