3659-66-3

Upstream product

• 515-82-2 chloralformamide 

Downstream Products

• 60029-23-4 N-(2,2,2-Trichloro-1-morpholino-ethyl) Formamide 
• 51360-91-9 1,1,1-Trichlor-2-phenylmercapto-2-formamino-aethan 
• 35801-40-2 N-(2,2,2-Trichloro-1-m-tolyloxy-ethyl)-formamide 
• 20856-55-7 N-(1-anilino-2,2,2-trichloro-ethyl)-formamide 
• 51360-94-2 N-(2,2,2-Trichloro-1-p-tolylsulfanyl-ethyl)-formamide 
• 51360-97-5 N-[2,2,2-Trichloro-1-(4-chloro-phenylsulfanyl)-ethyl]-formamide 
• 90794-00-6 1,1,1-Trichlor-2-benzylmercapto-2-formamino-ethan 
• 132370-94-6 N-{2,2,2-Trichloro-1-[N'-(2,6-diethyl-phenyl)-hydrazino]-ethyl}-formamide 
• 132370-93-5 N-{2,2,2-Trichloro-1-[N'-(2-ethyl-6-methyl-phenyl)-hydrazino]-ethyl}-formamide 
• 132370-92-4 N-<(2,2,2-trichloro-1-formylamino)ethyl>-2,6-dimethylphenylhydrazine 
• 36777-19-2 N-(2,2,2-trichloro-1-methoxy-ethyl)-formamide 
• 31896-37-4 N-{1-[(4-Bromo-phenyl)-(2-cyano-ethyl)-amino]-2,2,2-trichloro-ethyl}-formamide 
• 31896-26-1 N-[2,2,2-Trichloro-1-(isopropyl-phenyl-amino)-ethyl]-formamide 
• 31896-31-8 N-{2,2,2-Trichloro-1-[(4-chloro-phenyl)-methyl-amino]-ethyl}-formamide 

Relevant academic research and scientific papers

THE CRYSTAL AND ELECTRON STRUCTURE OF N-(2,2,2-TRICHLORO-1-MORPHOLINO-ETHYL) FORMAMIDE

The crystal structure was solved by direct methods and refined by the least squares method in a 9 x 9 block diagonal approximation using the anisotropic temperature parameters.The R-factor was decreased to a final value of 5.6percent for 970 observed reflextions.The crystal are monoclinic with a space group of P21/c and lattice parameters of a = 1.1056(11), b = 0.8913(11), c = 1.2023(16) nm, β = 96.32, and Z = 4.The crystal structure consists of discrete molecules between which hydrogen interactions of the N-HO and C-HO type were observed.The lengths of the N1-C3 (0.1432 nm) and C3-O1 (0.1203 nm) bonds and valence angles, C3-N1-C1 (119.9), N1-C3-O1 (126.5), indicate considerable delocalization of the ?-electrons and participation of the lone electrone pair on N1 nitrogen in the conjugation in the N1-C3-O1 molecular fragment.The CNDO/2 quantum chemical method was used to calculate the electron structure.Calculation for partial optimization of the dihedral angles, φ and ω, indicated that the most stable form is obtained for the values φ = 0, ψ = 120-150, 240-270 and ω = 150-210,330-30.