366002-40-6Relevant academic research and scientific papers
One-pot near-ambient temperature syntheses of aryl(difluoroenol) derivatives from trifluoroethanol
Kyne, Sara H.,Percy, Jonathan M.,Pullin, Robert D. C.,Redmond, Joanna M.,Wilson, Peter G.
supporting information; experimental part, p. 8328 - 8339 (2012/04/23)
Difluoroalkenylzinc reagents prepared from 1-(2′-methoxy- ethoxymethoxy)-2,2,2-trifluoroethane and 1-(N,N-diethylcarbamoyloxy)-2,2,2- trifluoroethane at ice bath temperatures underwent Negishi coupling with a range of aryl halides in a convenient one pot
Generating diversity in difluoromethyl ketone derivatives
DeBoos, Gareth A.,Fullbrook, Jeremy J.,Percy, Jonathan M.
, p. 2859 - 2861 (2007/10/03)
(equation presented) Two consecutive palladium-catalyzed coupling reactions from a readily available difluoroenol stannane set the stage for the synthesis of a range of difluoro-and halodifluoromethyl ketones upon a variable aryl template.
