366006-22-6Relevant academic research and scientific papers
Total synthesis of (-)-4a,5-Dihydrostreptazolin
Cossy, Janine,Pevet, Isabelle,Meyer, Christophe
, p. 2841 - 2850 (2001)
(-)-4a,5-Dihydrostreptazolin has been synthesized in nine steps from D-glyceraldehyde acetonide. Key steps include a diastereoselective addition of a vinylic Grignard reagent to an imine derived from D-glyceraldehyde acetonide, a ring-closing metathesis, and a stereoselective radical-mediated enyne cyclization.
