36617-81-9Relevant articles and documents
Asymmetric 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides catalyzed by a chiral rhodium complex
Oi, Shuichi,Taira, Akio,Honma, Yoshio,Sato, Takashi,Inoue, Yoshio
, p. 598 - 602 (2006)
A highly enantioselective 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides was successfully catalyzed by a chiral rhodium complex generated from [Rh(cod)(MeCN)2]BF4 and (S)-BINAP.