36635-80-0Relevant academic research and scientific papers
Synthesis of substituted cyclopropylphosphonates by Michael Induced Ring Closure (MIRC) reactions
Stevens, Christian V.,Van Heecke, Gino,Barbero, Carmen,Patora, Krystyna,De Kimpe, Norbert,Verhé, Roland
, p. 1089 - 1092 (2007/10/03)
A variety of cyclopropylphosphonates were prepared in moderate to good yields by Michael Induced Ring Closure of trialkyl phosphites with the corresponding β-bromoalkylidene cyanoacetates and malonates.
Single electron transfer in Michael induced ring closure reactions
Walborsky,Topolski
, p. 7681 - 7684 (2007/10/02)
Substituted cyclopropyl ether 3 is readily available from γ-bromoalkylidene malonate 2 via a Michael Induced Ring Closure (MIRC) reaction with sodium methoxide. Single Electron Transfer mechanism is suggested for the key cyclization step to account for th
