3668-74-4Relevant articles and documents
REACTION OF NITRILES WITH 100percent SULFURIC ACID. INFLUENCE OF THE STRUCTURAL EFFECTS OF NITRILES ON THE DIRECTION OF TRANSFORMATION, THE CHARACTER OF COMPLEX FORMATION, AND THE FORM OF THE KINETIC EQUATION
Bodrikov, I. V.,Michurin, A. N.,Vasyanina, G. I.,Bochkareva, N. N.,Krasnoj, V. L.
, p. 2123 - 2133 (2007/10/02)
The competing directions and kinetics were studied for the reactions of nitriles with 100percent sulfuric aicd.The donor-acceptor interaction between the nitriles and sulfuric acid and DMSO was also investigated.It was shown that variation in the structural effects of the nitriles gives rise to change in the form of the kinetic equation, the ratio between the competing reaction paths, and the character of the donor-acceptor interaction.Situations where the nitrile does not enter into the kinetic equation of the reaction are the most typical.Methods for directed control of the ratio between the competing paths are given.The probable schemes for the mechanism of the reactions are discussed.