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3669-50-9

1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one, also known as 2-phenyl-4'-hydroxy-2'-methylacetophenone, is an organic compound with the molecular formula C15H14O2. It is a derivative of acetophenone, featuring a phenyl group attached to a methylated hydroxyphenyl ring. This chemical is characterized by its molecular structure, which includes a ketone functional group (C=O) and a hydroxyl group (-OH). It is a white crystalline solid and is used in the synthesis of various pharmaceuticals, agrochemicals, and other organic compounds due to its versatile chemical properties. The compound's reactivity can be attributed to the presence of the phenyl and hydroxyl groups, which can participate in a range of chemical reactions, such as oxidation, reduction, and substitution.

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  • 3669-50-9 Structure

  • Basic information

    1. Product Name: 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one
    2. Synonyms: 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one
    3. CAS NO:3669-50-9
    4. Molecular Formula:
    5. Molecular Weight: 226.275
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 3669-50-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one(3669-50-9)
    11. EPA Substance Registry System: 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one(3669-50-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 3669-50-9(Hazardous Substances Data)

3669-50-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3669-50-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,6,6 and 9 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 3669-50:
(6*3)+(5*6)+(4*6)+(3*9)+(2*5)+(1*0)=109
109 % 10 = 9
So 3669-50-9 is a valid CAS Registry Number.

3669-50-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(4-hydroxy-2-methylphenyl)-2-phenylethan-1-one

1.2 Other means of identification

Product number -
Other names 4-Hydroxy-2-methyl-desoxybenzoin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3669-50-9 SDS

3669-50-9Relevant articles and documents

A convenient one-pot completely stereoselective synthesis of trans-4-Hydroxystilbenes and its derivatives and X-ray structure of its precursor

Chhor, Rakeshwar B.,Singh, Kunwar A.,Nosse,Tandon, Vishnu K.

, p. 2519 - 2530 (2007/10/03)

The synthesis of E-isomer of 4-Hydroxystilbene and its derivatives 3 by reductive elimination of the carbonyl function in 2-phenyl-1-(4-hydroxyphenyl)ethan-1-one and its derivatives 2 and the X-ray structure of 2a are described.

Selectivity in the photo-Fries reaction of phenyl phenylacetates included in a nation membrane

Tung, Chen-Ho,Xu, Xiao-He

, p. 127 - 130 (2007/10/03)

Photoirradiation of phenyl phenylacetates included within a Nafion membrane exclusively resulted in ortho-hydroxyphenones, thus achieving high selectivity in the photo-Fries reaction.

Photochemistry of phenyl phenylacetates adsorbed on pentasil and faujasite zeolites

Tung, Chen-Ho,Ying, Yun-Ming

, p. 1319 - 1322 (2007/10/03)

The photochemistry of phenyl phenylacetate 1, p-tolyl phenylacetate 2, o-tolyl phenylacetate 3 and phenyl o-tolylacetate 4 was investigated both in homogeneous solution and adsorbed on ZSM-5 and NaY zeolites.Photolyses of these esters in acetonitrile result in photo-Fries rearrangement products, phenols and diphenylethane as well as phenyl benzyl ethers.In contrast, photolyses of these esters adsorbed on NaY zeolite only give the ortho Fries rearrangemnt products.On the other hand, the photochemical reaction of 1 and 2 adsorbed on ZSM-5 zeolite only produces toluene and phenols, while under identical conditions the photochemical products for 3 and 4 are the Fries rearrangement and decarbonylation products. the product distributions for these esters adsorbed both on ZSM-5 and NaY zeolites are different from those for dibenzyl ketones as reported in the literature.All of these observations are interpreted in terms of (a) the size and shape sorption selectivity of ZSM-5 zeolite, (b) restriction of duffusional and rotational mobility of the radical pair imposed by the zeolite surface and (c) the multiplicity of the excited state responsible for the homolytic bond cleavage.

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