36712-21-7

Upstream product

• 186581-53-3 diazomethane 
• 3880-99-7 1-(13C)benzoic acid 
• 67-56-1 methanol 

Downstream Products

• 54522-91-7 [α-13C]-benzyl alcohol 
• 57742-41-3 <α-¹³C>Benzylchlorid 
• 75212-19-0 <2-¹³C>Phenylthioessigsaeure-O-<2-(2-hydroxyethoxy)ethylester> 
• 57742-43-5 Phenyl-<2-¹³C>acetaldehyd 
• 57742-42-4 Phenyl-<2-¹³C>acetaldehyd-diethylacetal 
• 75212-21-4 2-Phenyl<2-¹³C>thiiren 
• 75212-17-8 5-Phenyl-<5-¹³C>-1,2,3-thiadiazol 
• 75212-18-9 Phenyl-<2-¹³C>acetaldehyd-semicarbazon 
• 75212-20-3 <1-¹³C>Phenylthioessigsaeure-O-<2-(2-hydroxyethoxy)ethylester> 
• 20332-49-4 tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾ 
• 184490-77-5 [Ru(CO)2(P(C₆H₅)3)3] 

Relevant academic research and scientific papers

Acid-Catalyzed Degenerate Isomerization of Biphenyl

Biphenyl (1) has beeen synthesized in four steps from benzoic acid.Treatment of 1 with AlX3/H2O (X = Cl or Br) in benzene under a variety of conditions scrambles the isotopic label in the biphenyl.With 10:1 AlBr3/H2O as the catalyst, complet

Studies in Negative Ion Mass Spestrometry. XIV.- Electron Attachment Reactions of a Series of η6-Arenetricarbonylchromium(O) Complexes

Electron attachement rections of a series of (η6-arene)tricarbonylchromium(O) complexes have been examined in the gas phase.The electron capture process has been shown to be influenced by the structure of the η6-arene ligand and its

Experimental and Theoretical Studies on Gas-Phase Fragmentation Reactions of Protonated Methyl Benzoate: Concomitant Neutral Eliminations of Benzene, Carbon Dioxide, and Methanol

Protonated methyl benzoate, upon activation, fragments by three distinct pathways. The m/z 137 ion for the protonated species generated by helium-plasma ionization (HePI) was mass-selected and subjected to collisional activation. In one fragmentation path

Isomerization of Trimethyl α-Keto Trithioorthocarboxylates into α,α-Bis(methylthio) Thiolcarboxylates. A New Rearrangement of Synthetic Interest

A study was made of the isomerization reaction of a great variety of trimethyl α-keto trithioorthocarboxylates to α,α-bis(methylthio) thiolcarboxylates, intermediates of high synthetic value for the synthesis of α-arylpropionic acids. The reaction was carried out in methylene chloride in the presence of catalytic amounts of trityl perchlorate or methanesulfonic acid and was complete in 2 h at rt. In most of the investigated cases the result was positive, the yields usually being greater than 90%. Also the reaction mechanism was subjected to an experimental study.

The Formation of Phenylthiirene

Photolysis and thermolysis of 4- and 5-phenyl-13C>-1,2,3-thiadiazole (4a and 4a') furnish the phenylthioacetic acid O-esters 19 and 21, respectively, and the 1,3-dithioles 22.A product analysis by 13C NMR spectroscopy shows on the b