36727-46-5Relevant academic research and scientific papers
PALLADIUM-CATALYZED REGIO- AND STEREOSELECTIVE DESULFONYLATION OF ALLYLIC SULFONES WITH LiHBEt3. APPLICATION TO THE SYNTHESIS OF SQUALENE
Mohri, Mitsunobu,Kinoshita, Hideki,Inomata, Katsuhiko,Kotake, Hiroshi
, p. 451 - 454 (1985)
Allylic p-tolyl sulfones were easily desulfonylated to the corresponding alkenes by LiHBEt3 in the presence of a catalytic amount of under mild conditions with the preservation of the original stereochemistry.This reaction was successfully applied to the synthesis of squalene.
