36729-31-4Relevant academic research and scientific papers
Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C-H/N-O Functionalization with Nitrones
Wang, Hui,Moselage, Marc,González, María J.,Ackermann, Lutz
, p. 2705 - 2709 (2016/04/26)
The redox-neutral annulation of alkynes by differently decorated nitrones set the stage for a step-economical access to indoles with ample substrate scope. The redox-neutral C-H/N-O functionalization process proceeded through kinetically relevant C-H activation by carboxylate assistance, and displayed an excellent site- and regio-selectivity with unsymmetrical nitrones and alkynes.
