36742-36-6Relevant articles and documents
Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates
Zhou, Jianrong Steve,Huang, Xiaolei,Teng, Shenghan,Chi, Yonggui Robin
supporting information, p. 3933 - 3936 (2021/04/26)
Nickel-catalyzed Heck reaction of cycloalkenes delivers unusual conjugated arylated isomers. Nickel(0) catalysts ligated by chelating dialkylphosphines effectively activate not only aryl triflates as electrophiles, but also less reactive aryl mesylates, t
Arenediazonium o-benzenedisulfonimides as efficient reagents for Heck-type arylation reactions
Artuso, Emma,Barbero, Margherita,Degani, Iacopo,Dughera, Stefano,Fochi, Rita
, p. 3146 - 3157 (2007/10/03)
Arenediazonium o-benzenedisulfonimides can be used as new and efficient reagents for Heck-type arylation reactions of some common substrates containing C-C multiple bonds, namely ethyl acrylate, acrylic acid, acroleyne, styrene and cyclopentene. The reactions were carried out in an organic solvent, in the presence of Pd(OAc)2 as pre-catalyst, and gave rise to arylated products, for example, ethyl cinnamates, cinnamic acids, cinnamic aldehydes and stilbenes, possessing an (E)-configuration, and 1-arylcyclopentenes, in good to excellent yields. It is noteworthy that all the reactions led to the recovery, in greater than 80% yield, of o-benzenedisulfonimide, recyclable for the preparation of other diazonium salts.
Synthesis and pharmacological activity of 6-aryl-2-azabicyclo[4.2.1]nonanes
Mazzocchi,Kim
, p. 1473 - 1476 (2007/10/02)
A series of 6-phenyl-, 6-(m-methoxyphenyl)- and 6-(m-hydroxyphenyl)-2-azabicylo[4.2.1]nonanes was synthesized by a sequence involving alkylation of an appropriate 2-arylcyclopentanone with an aminoalkyl substituent. Subsequent ring closure at the other α