36748-82-0

Upstream product

• 5195-30-2 3-methyl-5-phenyl-2-pentanone 
• 38795-58-3 2-methyl-4-phenylbutyric acid methyl ester 
• 917-54-4 methyllithium 
• 66928-64-1 2,3-dimethyl-2-phenethyl-oxirane 
• 1210492-28-6 C₁₂H₁₆O 
• 242483-39-2 2-methyl-4-phenyl-butyryl chloride 
• 1771-65-9 2-methyl-4-oxo-4-phenylbutanoic acid 
• 1949-41-3 2-methyl-4-phenylbutanoic acid 

Relevant academic research and scientific papers

Palladium-Catalyzed isomerization of exo-methylenic allylic alcohols

Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.

Sustainable radical reduction through catalyzed hydrogen atom transfer reactions (CHAT-reactions)

A system with coupled catalytic cycles is described that allows radical reduction by catalyzed hydrogen atom transfer (CHAT) from transition metal hydrides. These intermediates are generated through H2 activation. Radical generation is carried out by titanocene catalyzed electron transfer to epoxides. The reaction provides a novel entry into the atom-economical reduction of radicals that has long been considered as a critical issue for the industrial application of radical chemistry.