36791-67-0

Basic information

• Product Name: 2-(tert-butylimino)-3-methyl-4-tosylimino-1,3-thiazetidine
• Synonyms: 2-(tert-butylimino)-3-methyl-4-tosylimino-1,3-thiazetidine
• CAS NO: 36791-67-0
• Molecular Weight: 325.456
• Mol File: 36791-67-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(tert-butylimino)-3-methyl-4-tosylimino-1,3-thiazetidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(tert-butylimino)-3-methyl-4-tosylimino-1,3-thiazetidine(36791-67-0)
• EPA Substance Registry System: 2-(tert-butylimino)-3-methyl-4-tosylimino-1,3-thiazetidine(36791-67-0)

Safety Data

• Hazardous Substances Data: 36791-67-0(Hazardous Substances Data)

Upstream product

• 25347-94-8 N-tert-Butyl-N'-methylharnstoff 
• 19411-70-2 N-tert-butyl-N'-methylcarbodiimide 
• 1424-52-8 p-tolylsulfonyl isothiocyanate 

Downstream Products

• 77802-81-4 N-[1-(3-tert-Butyl-1-methyl-thioureido)-1-dimethylamino-meth-(Z)-ylidene]-4-methyl-benzenesulfonamide 
• 77802-80-3 N-[2-[(E)-tert-Butylimino]-3-methyl-5-phenyl-2,3-dihydro-[1,3]thiazin-(4Z)-ylidene]-4-methyl-benzenesulfonamide 
• 21017-78-7 N-(p-Tosyl)-N'-methyl-S-ethyl isothiourea 
• 77802-76-7 tert-Butyl-dithiocarbamic acid ethyl ester 
• 590-42-1 tert-butyl isothiocyanate 
• 77802-78-9 2-{Methylamino-[(Z)-toluene-4-sulfonylimino]-methyl}-malonic acid diethyl ester 
• 83324-98-5 2-[(E)-tert-Butylimino]-1,3-dimethyl-4-[(E)-toluene-4-sulfonylimino]-azetidine-3-carboxylic acid ethyl ester 
• 3878-45-3 triphenylphosphine sulfide 
• 19411-70-2 N-tert-butyl-N'-methylcarbodiimide 
• 83325-00-2 3-[(E)-Toluene-4-sulfonylimino]-2-(triphenyl-λ⁵-phosphanylidene)-pentanedioic acid diethyl ester 
• 83325-01-3 N-[1-(3-tert-Butyl-1-methyl-thioureido)-2-phenyl-2-(triphenyl-λ⁵-phosphanylidene)-eth-(Z)-ylidene]-4-methyl-benzenesulfonamide 
• 77802-83-6 N-[2-[4-[(Z)-tert-Butylimino]-3-methyl-[1,3]thiazetidin-(2Z)-ylidene]-1-diethylamino-prop-(E)-ylidene]-4-methyl-benzenesulfonamide 
• 77802-82-5 N-[2-[(E)-tert-Butylimino]-6-diethylamino-3,5-dimethyl-2,3-dihydro-[1,3]thiazin-(4E)-ylidene]-4-methyl-benzenesulfonamide 
• 77802-79-0 1-tert-butyl-5-(methylamino)tetrazole 

Relevant articles and documents

REACTIONS OF 2-(TERT-BUTYLIMINO)-3-METHYL-4-TOSYLIMINO-1,3-THIAZETIDINE

This paper describes the reactivity of the title bis(imino)thiazetidine in terms of three reactivity centers of the molecule; C2, C4 and C=NTs.Reactions have been carried out with nucleophilic reagents (NaOMe, NaSEt, KCN and malonic ester/DMSO/NaH), hydrazoic acid and electron-rich olefins (enamines and ynamines), giving rise to products 2-10.The two products, 9 and 10, obtained in equal amounts from 1 and N,N-diethylaminopropyne have been subjected to a detailed analysis by spectral methods and the structure of one of them (10) has been confirmed by the determination of its crystal structure.