77802-80-3Relevant academic research and scientific papers
REACTIONS OF 2-(TERT-BUTYLIMINO)-3-METHYL-4-TOSYLIMINO-1,3-THIAZETIDINE
Sorgeloos, Dominique,Toppet, Suzanne,King, Geoffrey S. D.,Meervelt, Luc Van
, p. 63 - 74 (2007/10/02)
This paper describes the reactivity of the title bis(imino)thiazetidine in terms of three reactivity centers of the molecule; C2, C4 and C=NTs.Reactions have been carried out with nucleophilic reagents (NaOMe, NaSEt, KCN and malonic ester/DMSO/NaH), hydrazoic acid and electron-rich olefins (enamines and ynamines), giving rise to products 2-10.The two products, 9 and 10, obtained in equal amounts from 1 and N,N-diethylaminopropyne have been subjected to a detailed analysis by spectral methods and the structure of one of them (10) has been confirmed by the determination of its crystal structure.
