36795-97-8Relevant articles and documents
Gold(I)-Catalyzed Intermolecular Rearrangement Reaction of Glycosyl Alkynoic β-Ketoesters for the Synthesis of 4- O-Glycosylated 2-Pyrones
Liu, Rongkun,Li, Xiaoqian,Li, Xiaona,Wang, Jiazhe,Yang, You
, p. 14141 - 14150 (2019)
A new gold(I)-catalyzed rearrangement reaction with glycosyl alkynoic β-ketoesters as substrates is developed. The rearrangement reactions under the catalysis of PPh3AuOTf proceeded smoothly to afford a range of 4-O-glycosylated 2-pyrones. Base