Journal of Organic Chemistry p. 14141 - 14150 (2019)
Update date:2022-08-05
Topics:
Liu, Rongkun
Li, Xiaoqian
Li, Xiaona
Wang, Jiazhe
Yang, You
A new gold(I)-catalyzed rearrangement reaction with glycosyl alkynoic β-ketoesters as substrates is developed. The rearrangement reactions under the catalysis of PPh3AuOTf proceeded smoothly to afford a range of 4-O-glycosylated 2-pyrones. Base
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