36799-70-9

Basic information

• Product Name: Ir(CO)(NCOC₂H₄CO)(P(C₆H₅)3)2
• CAS NO: 36799-70-9
• Molecular Weight: 842.893
• Mol File: 36799-70-9.mol

Chemical Properties

• CAS DataBase Reference: Ir(CO)(NCOC₂H₄CO)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(CO)(NCOC₂H₄CO)(P(C₆H₅)3)2(36799-70-9)
• EPA Substance Registry System: Ir(CO)(NCOC₂H₄CO)(P(C₆H₅)3)2(36799-70-9)

Safety Data

• Hazardous Substances Data: 36799-70-9(Hazardous Substances Data)

Upstream product

• 123-56-8 Succinimide 
• 15318-31-7 bis(triphenylphosphine)iridium(I) carbonyl chloride 

Relevant articles and documents

Transition Metal Complexes with Terminal or Bridging Imidato(1-) Ligands. X-Ray Crystal Structures of trans- and 2>*CH2Cl2, Spectroscopic Studies of , and the Nature of the Metal-Nitrog...

The reaction of with the thallium(I) salt of succinimide yields the novel succinimidato(1-) complex .The imide-derived ligand is found to behave as a pseudo-halogen in terms of its ?-acceptor and ?-donor properties by 'Graham' analysis of i.r. spectroscopic data.Mononuclear arylpalladium complexes, trans- , and related carbonyl-rhodium and -iridium complexes, trans-, may be synthesised by reaction of the corresponding chloro-complexes with succinimide, phthalimide, or tetrafluorosuccinimide.The structure of trans- has been established crystallographically (Ir-N 2.09 Angstroem).Binuclear arylpalladium complexes containing halide or acetate bridges react with imides in the presence of base to give complexes in which the imidato(1-) ligand adopts a novel bridging co-ordination mode, via nitrogen and one of the carbonyl oxygens.The structure of one complex of this type, 2>*CH2Cl2, has been confirmed crystallographically.