368-47-8Relevant academic research and scientific papers
Phenyl(fluoro)chlorodisiloxanes
Basenko,Zelenkov,Voronkov,Albanov
experimental part, p. 242 - 244 (2010/08/05)
Cohydrolysis of phenyltrichlorosilane with phenyl(fluoro)dichloro- and phenyl(difluoro)-chlorosilanes and thermolysis of the formed siloxanes leading to the formation of phenyl(difluoro)chlorosilane are studied. The scheme of thermal decomposition of disi
Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis
Kunai, Atsutaka,Ohshita, Joji
, p. 3 - 15 (2007/10/03)
Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X=Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo- and bromosilanes and germanes were obtained by Pd- or Ni-catalyzed hydride-halogen exchange reactions of hydrosilanes with alkyl or allyl halides. Their synthetic applications have been demonstrated by using iodo- and bromosilanes and chlorofluorosilanes.
DARSTELLUNG UND CHARAKTERISIERUNG DER PHENYLFLUORDISILANE Si2Ph6-nFn
Hengge, E.,Schrank, F.
, p. 1 - 8 (2007/10/02)
Fluorination of chlorophenyldisilanes with ZnF2 yields the corresponding fluorophenyldisilanes, if silver powder is used as a catalyst. 1,2-Difluorotetraphenyldisilane is synthesized by UV irradiation of bis-(fluorodiphenylsilyl)mercury, the first known fluorosilylmercury compound.All the eight possible fluorophenyldisilanes, unknown up to now, are characterized by spectroscopic methods.
