7783-56-4Relevant articles and documents
Study of the reaction of dichloromethane with hydrogen fluoride in the presence of antimony chlorofluorides
Vinogradov,Khomutov
, p. 359 - 365 (2000)
The reaction of dichloromethane with hydrogen fluoride in the presence of antimony chlorofluorides is studied in the setup for liquid-phase synthesis. The reaction type, orders with respect to reactants and the catalyst, and Arrhenius parameters are deter
Polar trifluoromethylation reactions. Synthesis and NMR spectra of tris(trifluoromethyl)antimony, Sb(CF3)3
Naumann, Dieter,Tyrra, Wieland,Leifeld, Ferdinand
, p. 193 - 198 (1987)
Bis(trifluoromethyl)cadmium complexes react with antimony trihalides in polar solvents to form Sb(CF3)3 in high yield.The reactions proceed stepwise and the mono- and bis(trifluoromethyl)antimony compounds formed as intermediates have been identified from
Ptaszynski, B.
, p. 173 - 182 (1981)
Complex antimony(III) oxohalides: Synthesis and physicochemical properties
Panasenko,Zemnukhova,Kavun,Merkulov
, p. 163 - 168 (2012/06/15)
Complexes of the formula MSb2BrF4O (M = K, Rb, and NH4) were obtained from aqueous solutions of SbF3 and MBr and examined by chemical analysis, X-ray diffraction, thermal analysis, and IR, Raman, and 19F NMR spectroscopy. It was found that the red reflectance is 74-97% and the UV reflectance is 7-15%. The highest averaged reflectance (93%) was observed for KSb2BrF4O. The decomposition temperatures of MSb2BrF4O (M = K, Rb, and NH4) are 230, 197, and 223°C, respectively. Pleiades Publishing, Ltd., 2012.