368423-20-5Relevant articles and documents
Radical Fragmentation of β-Hydroxy Azides. Synthesis of Chiral Nitriles
Hernandez, Rosendo,Leon, Elisa I.,Moreno, Pilar,Suarez, Ernesto
, p. 8974 - 8975 (1997)
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Transformation of peroxide products of olefin ozonolysis under treatment with hydroxylamine and semicarbazide hydrochlorides in acetic acid
Ishmuratov,Legostaeva,Garifullina,Botsman,Muslukhov,Tolstikov
, p. 1075 - 1081 (2015/02/02)
Hydrochlorides of hydroxylamine and semicarbazide efficiently reduce peroxide products of olefin ozonolysis in a system CH2Cl2-AcOH leading to the formation of carboxylic acids and their derivatives. The application of water as the solvent component favors the increase in the fraction of nitrogen-containing organic compounds (semicarbazones, keto- and aldoximes, nitriles) and reduction in the yield of carboxylic acids.
Synthesis of highly functionalized chiral nitriles by radical fragmentation of β-hydroxy azides. Convenient transformation of aldononitriles into 1,4- and 1,5-iminoalditols
Hernandez, Rosendo,Leon, Elisa I.,Moreno, Pilar,Riesco-Fagundo, Concepcion,Suarez, Ernesto
, p. 8437 - 8444 (2007/10/03)
The synthesis of highly functionalized nitriles by an alkoxyl radical fragmentation of cyclic β-hydroxy azides is described. The alkoxyl radicals were generated by reaction of the alcohols with (diacetoxyiodo)benzene and iodine under mild conditions compa