36854-14-5Relevant academic research and scientific papers
A general and selective iron-catalyzed aminocarbonylation of alkynes: Synthesis of acryl- and cinnamides
Driller, Katrin Marie,Prateeptongkum, Saisuree,Jackstell, Ralf,Beller, Matthias
supporting information; experimental part, p. 537 - 541 (2011/03/16)
Entering the iron age: The first general method for iron-catalyzed monocarbonylation of alkynes has been developed. A range of structurally diverse cinnamides and acrylamides have been obtained smoothly starting from commercially available amines and alkynes in the presence of [Fe 3(CO)12] and ligand L (see scheme). The method is highly chemo- and regioselective and requires no expensive catalyst.
On the Reaction of Diphenylcyclopropenone, its Functional Derivatives and Imonium Salts with Amines
Eicher, Theophil,Boehm, Siegfried,Ehrhardt, Heinz,Harth, Robert,Lerch, Dieter
, p. 765 - 788 (2007/10/02)
The reactions of cyclopropenones 1, 2, cyclopropenone imines 3 and cyclopropenone imonium cations 5 with amines of different type are investigated and the structure of the products obtained is elucidated by means of spectral data and chemical behavior.The possible reaction modes and mechanisms are discussed.
