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Codeine N-oxide is a chemical compound derived from codeine, an opioid analgesic used to treat mild to moderate pain. It is formed as a result of the oxidation of codeine, which occurs during its metabolism in the liver. Codeine N-oxide has been found to have similar pharmacological properties to codeine, such as pain-relieving and cough-suppressing effects, but it is generally considered to be less potent. The compound is also of interest in research due to its potential role in understanding the metabolic pathways of codeine and its derivatives. It is important to note that, like codeine, Codeine N-oxide has the potential for abuse and addiction, and its use should be carefully monitored.

3688-65-1

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3688-65-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3688-65-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,6,8 and 8 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 3688-65:
(6*3)+(5*6)+(4*8)+(3*8)+(2*6)+(1*5)=121
121 % 10 = 1
So 3688-65-1 is a valid CAS Registry Number.
InChI:InChI=1/C18H21NO4/c1-19(21)8-7-18-11-4-5-13(20)17(18)23-16-14(22-2)6-3-10(15(16)18)9-12(11)19/h3-6,11-13,17,20H,7-9H2,1-2H3/t11-,12+,13-,17-,18-,19?/m0/s1

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  • (1143802)  Codeine N-oxide  United States Pharmacopeia (USP) Reference Standard

  • 3688-65-1

  • 1143802-50MG

  • 6,162.39CNY

  • Detail

3688-65-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Codeine N-Oxide

1.2 Other means of identification

Product number -
Other names (3S,4R,4aR,7S,7aR,12bS)-9-methoxy-3-methyl-3-oxido-2,4,4a,7,7a,13-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinoline-3-ium-7-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3688-65-1 SDS

3688-65-1Upstream product

3688-65-1Downstream Products

3688-65-1Relevant academic research and scientific papers

Efficient N-Demethylation of Opiate Alkaloids Using a Modified Nonclassical Polonovski Reaction

McCamley, Kristy,Ripper, Justin A.,Singer, Robert D.,Scammells, Peter J.

, p. 9847 - 9850 (2007/10/03)

A modified Polonovski reaction has been employed to N-demethylate several opiate alkaloids in moderate to high yield. This method provides an alternative to traditional N-demethylation procedures which utilize toxic reagents such as cyanogen bromide or expensive reagents such as vinyl chloroformate. The current synthesis involves N-oxide formation, isolation of the corresponding N-oxide hydrochloride, and an FeS04·7H20 mediated Polonovski reaction to afford the desired secondary amine.

ENZYMATIC TRANSFORMATIONS OF MORPHINANE ALKALOIDS

Vagujfalvi, Dezsoe,Petz-Stifter, Maria

, p. 1533 - 1536 (2007/10/02)

Horseradish peroxidase transforms morphinane alkaloids into N-oxides and morphine to pseudomorphine in the presence of hydrogen peroxide.The crude poppy enzyme fraction shows the same activities.The rates of reactions were influenced by phenolic compounds and their relation controlled by the concentration of hydrogen peroxide and the presence of ascorbic acid. - Key Word Index: Papaver somniferum; Papaveraceae; morphine; codeine; thebaine; morphinane N-oxides; pseudomorphine; peroxidase; poppy enzyme fraction; phenolcarboxylic acids; ascorbic acid.

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