36896-63-6

Basic information

• Product Name: Aluminum, (benzenethiolato)dimethyl-
• CAS NO: 36896-63-6
• Molecular Formula: C8H11AlS
• Molecular Weight: 166.223
• Mol File: 36896-63-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Aluminum, (benzenethiolato)dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Aluminum, (benzenethiolato)dimethyl-(36896-63-6)
• EPA Substance Registry System: Aluminum, (benzenethiolato)dimethyl-(36896-63-6)

Safety Data

• Hazardous Substances Data: 36896-63-6(Hazardous Substances Data)

Upstream product

• 75-24-1 trimethylaluminum 
• 108-98-5 thiophenol 

Downstream Products

• 36921-35-4 C₈H₁₂Ni(S(C₆H₅)Al(CH₃)2)2 
• 116645-28-4 7-[(2R,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-oxo-2-phenylsulfanyl-cyclopent-(Z)-ylidene]-hept-5-ynoic acid methyl ester 
• 286930-15-2 2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester 
• 368446-12-2 methyl (7S)-3,5,7-tri-O-acetyl-7-C-[(1R,2S,3R,4S,5R,7S)-2-endo-(acetyloxy)-7-endo-(benzyloxy)-6-oxo-4-exo-(phenylthio)-8-oxabicyclo[3.2.1]oct-3-endo-yl]-2,6-anhydro-4-O-benzoyl-L-glycero-D-manno-heptonate 
• 304678-71-5 (S)-4-tert-Butyl-3-((1S,2R,4R,6R)-2-hydroxy-4-methyl-6-phenylsulfanyl-cyclohexanecarbonyl)-oxazolidin-2-one 
• 85048-06-2 (E)-13-Phenylsulfanyl-azacyclotridec-13-ene 
• 85028-13-3 N-Phenyl-thioacetimidic acid phenyl ester 
• 131454-95-0 2-endo-Acetamido-2-exo-phenylthionorbornene 
• 131454-95-0 2-exo-Acetamido-2-endo-phenylthionorbornene 

Relevant articles and documents

Synthesis and structural characterization of polymeric dimethylaluminum phenylthiolate

The reaction of trimethylaluminum with thiophenol forms the compound [Me2Al(μ-SPh)]n in good yield. The compound has been characterized by 1H, 13C and variable-temperature NMR (VT-NMR) spectroscopy, mass spectroscopy, and by cryoscopic molecular-weight determination. The solid-state structure has been determined by single-crystal X-ray crystallography and was assigned to the monoclinic space group Pc (no. 7) with cell constants a=9.2499(12), b=7.1344(10), c=7.1947(11) A?, β=100.328(3)° and Z=2. The refinement converged with R1=7.24% (wR2=15.4%) for 581 (I≥2σ(I)) observed reflections and was described in terms of an infinite chain polymer with phenyl thiol groups and dimethylaluminum groups alternating. The average Al-S distance is 2.36 A?. VT-NMR shows that the compound exhibits some fluxional behavior, which affects the ortho protons of the phenyl ring. Cryoscopic molecular-weight measurements show that the aggregation state is a function of concentration, and it has been proposed that two species, dimer and trimer, exist in solution.

Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent

Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi