36909-55-4

Basic information

• Product Name: 2-Propanone bis(1-methylethyl)hydrazone
• Synonyms: 2-Propanone bis(1-methylethyl)hydrazone;Acetone diisopropyl hydrazone
• CAS NO: 36909-55-4
• Molecular Formula: C₉H₂₀N₂
• Molecular Weight: 0
• Mol File: 36909-55-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propanone bis(1-methylethyl)hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone bis(1-methylethyl)hydrazone(36909-55-4)
• EPA Substance Registry System: 2-Propanone bis(1-methylethyl)hydrazone(36909-55-4)

Safety Data

• Hazardous Substances Data: 36909-55-4(Hazardous Substances Data)

Upstream product

• 110-05-4 di-tert-butyl peroxide 
• 15464-00-3 azobisisopropane 
• 921-14-2 N,N-diisopropylhydrazine 
• 67-64-1 acetone 

Downstream Products

• 49840-64-4 N,N',N'-Triisopropyl-N-methyl-hydrazine 

Relevant articles and documents

A kinetic study of the reaction between CH3 radicals and azoisopropane; reactions of the radicals CH3, (CH3)2 CN = NCH(CH3)2 and (CH3)2CH NN(CH3)CH(CH3)2

The reaction of CH3 generated from di-tert-butyl peroxide with azoisopropane (AIP) in the temperature range 395-450 K was investigated by product analysis. The regioselectivity of CH3 with the carbon and nitrogen radical centres of (CH3)2 CN=NCH(CH3)2 was determined: CH3 + (CH3)2CN=NCH(CH3)2 → (CH3)3CN=NCH(CH3)2 (18) → (CH3)2C=NN(CH3)CH(CH3)2 (19) k18/k19 = 1.95 ± 0.24. The Arrhenius parameters of the H-abstraction and decomposition reactions CH3 + AIP → CH4 + (CH3)2CN=NCH(CH3)2 (3) (CH3)2CHNN(CH3)CH(CH3)2 → 2- CH7 + (CH3)2CHN=NCH3 (23) relative to the combinations 2 CH3 → C2H6 (13) 2 (CH3)2CHNN(CH3)CH(CH3)2 → (CH3)2CHN(CH3)N(CH(CH3)2)N(CH(CH3)2)N(CH3)CH(CH3)2 (26) were determined: log[(k3/, k13/(1/2)) / mol(-1/2) dm(3/2)s(-1/2)] = (3.1 ± 0.3) - (30.6 ± 2.4) kJ mol-1/θ log[k23 (φ k26/(1/2))- 1/mol(1/2)dm(-3/2)s(-1/2)] = (8.8 ± 0.5) - (110.0 ± 6.5) kJ mol-1/θ where θ = RT In 10 and φ is the cross-combination ratio of CH3 and (CH3)2CHNN(CH3)CH(CH3)2.