369390-74-9

Upstream product

• 66127-01-3 3-bromophenanthroline 
• 369390-65-8 3-(2-(trimethylsilyl)ethynyl)-1,10-phenanthroline 
• 369390-68-1 2,9-Bis(2,4,6-trimethylphenyl)-3-(trimethylsilanylethynyl)-[1,10]phenanthroline 
• 624-38-4 para-diiodobenzene 
• 369390-71-6 2,9-Bis(2,4,6-trimethylphenyl)-3-ethynyl-[1,10]phenanthroline 

Relevant academic research and scientific papers

Synthesis of soluble, linear bisphenanthrolines for the construction of heteroleptic nanoGrids and nanoboxes

The preparation of several new and soluble bisphenanthrolines that are important building blocks for various supramolecular structures based on heteroleptic copper(I) complexes is described.

Synthesis of macrocyclic phenanthrolines with exotopic binding sites. Probing Their complexation behavior with copper(I) and iron(II)

Starting from 4,7-dichlorophenanthroline (1) a synthetic approach is developed to novel macrocyclic mono- and bisphenanthrolines (5a-d, 6a-d) with exotopic binding sites. As these coordinating compounds are characterized by a flexible spacer unit, their utility as ligand for the construction of oligomeric, dendritic and box-like structures in the presence of copper(I) and iron(II) is evaluated. Spectroscopic data suggest that with copper(I) the [1+1] adduct [Cu2(6c)(7)]2+ is formed. Wiley-VCH Verlag GmbH, 1999.