3694-33-5

Upstream product

• 90-02-8 salicylaldehyde 
• 616-29-5 1,3-Diamino-2-hydroxypropane 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 145522-01-6 N,N'-bis(2-hydroxybenzyl)-2-hydroxypropane-1,3-diamine 

Relevant academic research and scientific papers

Synthesis, characterization, superoxide dismutase, and antimicrobial activities of Co (II) complexes with Schiff base ligand and their hybrid proteins

Metal complexes have been reported to possess excellent free radical scavenging and antimicrobial properties. In the present study, seven linear trinuclear complexes were synthesized based on bis Schiff base ligand and complexes 1, 3–7 are reported for th

A bowl-shaped phenoxido-bridged binuclear zinc complex: Experimental and theoretical studies

A new dinuclear zinc coordination complex with di(μ-alkoxido) bridge obtained from [[H2L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol] was investigated by IR, 1H- & 13C NMR spectroscopy. Single crystal X-ray analysis reveal

Transesterification activity by a zinc(II)-Schiff base complex with theoretical interpretation

The article demonstrates the synthesis, structural characterization and transesterification activity of a mononuclear zinc(II) complex, [Zn(HL)(H2O)]·(H2O) (1) containing a previously reported Schiff base ligand, H3L = N,N

Synthesis, structural and DFT interpretation of a Schiff base assisted Mn(III) derivative

A mononuclear MnIII derivative, [Mn(L)(SCN)(H2O)] (1) [where H2L = N,N′-bis(salicyaldehydene)-1,3-diaminopropan-2-ol] has been synthesized and systematically characterized. In 1, the central MnIII ion is linked

Oxidative cleavage of DNA by transition metal complexes: Synthesis, spectral characterization and DNA interactions of copper(II) complexes with quinquedentate Schiff base ligands

Designing of dinucleating ligands, with an additional donor atom that can bridge two metals in a more or less fixed geometry has rapidly developed in recent years. Part of the interest stems from the fact that the corresponding complexes are often studied

The effect of metal and substituent on DNA binding, cleavage activity, and cytotoxicity of new synthesized Schiff base ligands and Zn(II) complex

New water soluble Schiff base ligands [N,N?-bis{5-[(triphenylphosphonium percholorate)-methyl]salicylidine}-1,3-diamino-2-propanol] (L1) and [N,N?-bis(salicylidine)-1,3-diamino-2-propanol] (L2) and zinc (II) complex of L1: [N,N?-bis{5-[(triphenylphosphonium percholorate)-methyl]salicylidine}-1,3-diamino-2-propanol]Zn(II) were synthesized and characterized by elemental analysis, FT-IR, 1HNMR and UV–Vis spectroscopy. In vitro DNA binding of the compounds were investigated by UV–Vis absorption spectroscopy, viscosity measurement, cyclic voltammetry, fluorescence spectroscopy, and gel electrophoresis. The present study aimed to investigate the effect of metal and substituent on DNA binding, cleavage activity and cytotoxicity of new synthesized Schiff base ligands and Zn(II) complex. The order of DNA binding affinity (Kb) calculated from the absorption spectroscopy was: ZnL1 > L2 > L1. Molecular docking studies explore more details on the mode of binding and binding energies. Although the compounds revealed strong DNA binding affinity but electrophoresis studies don't show any effects on the DNA structure and single or double strand breaks. The cytotoxicity experiments against human Hepatoma (HepG2) showed the order: L1 > ZnL1 > L2.

Antiferro- to ferromagnetic crossover in diphenoxido bridged NiII2MnII complexes derived from N2O2 donor Schiff base ligands

Three new trinuclear NiII-MnII complexes have been synthesized using three different "metalloligands" [NiL1], [NiL2] and [NiL3] derived from the Schiff bases H2L1 = N,N′-bis(salicylidene)-1,3-pentanediamine, H2L2 = N,N′-bis(salicylidene)-1,3-propanediamine and H2L3 = N,N′-bis(salicylidene)-1,3,-diaminopropan-2-ol), respectively. In all three complexes, [(NiL1)2Mn(OOCPh)2(H2O)2]·CH3OH (1), [(NiL2)2Mn(OOCPh)2(CH3OH)2]·CH3OH (2) and [(NiL3)2Mn(OOCPh)2(H2O)2]·CH3OH (3), in addition to the double phenoxido bridge, the two terminal NiII atoms are linked to the central MnII by means of a syn-syn bridging benzoate, giving rise to a linear structure. Complex 1 with Ni-O-Mn angle of 97.35° exhibits antiferromagnetic interactions (JNi-Mn = -0.60 cm-1) whereas ferromagnetic exchange is observed in 2 and 3 (JNi-Mn = +2.00 and +1.10 cm-1 respectively) having Ni-O-Mn angle 97.34° (in 2), 97.27° (in 3). Theoretical calculations have been performed in order to understand the effect of structural parameters that can tune the magnetic properties of this type of complexes such as small differences in the Ni-O-Mn angle and/or slight variations in intermolecular contacts within the crystal.

40-44 Pd(II) salen complex covalently anchored to multi-walled carbon nanotubes as a heterogeneous and reusable precatalyst for Mizoroki-Heck and Hiyama cross-coupling reactions

A Pd(II) salen complex anchored to multi-walled carbon nanotubes showed excellent catalytic activity and stability for the Mizoroki-Heck and Hiyama cross-couplings of aryl halides with olefins and phenylsiloxanes. Furthermore, the heterogeneous catalyst could be reused up to four times with the catalytic activity being recovered easily after simple manipulations.

A perfectly linear trinuclear zinc-Schiff base complex: Synthesis, luminescence property and photocatalytic activity of zinc oxide nanoparticle

A perfectly linear trinuclear zinc(II) complex [Zn3L 2(μ-O2CCH3)2] (1) containing a (N,O)-donor Schiff base ligand, (H2L = N,N′- bis(salicyaldehydene)-1,3-diaminopropan-2-ol) has been synth

Synthesis, X-ray structural and magnetic characterizations, and epoxidation activity of a new bis(μ-acetato)(μ-alkoxo)dinuclear iron(III) complex

The synthesis, crystal structure and variable temperature magnetic measurements of a new dinuclear Fe(III) complex, [Fe2(μ 1,3-O2Cfn)(OH2)(MeOH)Cl2L] (1) [fn = furan, L = N,N′-bis(salicyaldehydene)-1,