36960-12-0Relevant academic research and scientific papers
InCl3/Me3SiCl-catalyzed direct michael addition of enol acetates to α,β-unsaturated ketones
Onishi, Yoshiharu,Yoneda, Yuki,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information, p. 5788 - 5791 (2013/01/15)
The direct Michael addition of enol acetates to α,β-unsaturated ketones was achieved using a combination of Lewis acid catalysts, InCl 3 and Me3SiCl, which furnished stable enol-form products that could be further transformed into functionalized 1,5-diketones by reactions with various electrophiles.
InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates
Onishi, Yoshiharu,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 2762 - 2765 (2011/08/02)
A combined Lewis acid catalyst of InCl3 and Me3SiBr promoted the direct use of enol acetates in the coupling with low-reactive silyl ethers, in which functional groups including ketones and aldehydes survived. Sterically hindered silyl ethers such as ROSiEt3, ROSiPh3, ROSit-BuMe2, and ROSii-Pr3 were also applicable.
