36989-07-8

Basic information

• Product Name: 1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane
• Synonyms: 1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane
• CAS NO: 36989-07-8
• Molecular Weight: 342.431
• Mol File: 36989-07-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane(36989-07-8)
• EPA Substance Registry System: 1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane(36989-07-8)

Safety Data

• Hazardous Substances Data: 36989-07-8(Hazardous Substances Data)

Upstream product

• 23841-96-5 1-lithium-1,2-dicarba-closo-dodecaborane⁽¹²⁾ 
• 57137-53-8 (chloromethyl)diphenylphosphane 

Downstream Products

• 98-83-9 isopropenylbenzene 
• 19342-01-9 (S)-N,N-dimethyl-1-phenylethylamine 
• 17279-31-1 (-)-(S)-N,N-dimethyl-1-phenylethylamine 
• 187737-37-7 propene 
• 103-83-3 N,N'-dimethylbenzylamine 

Relevant articles and documents

INTRAMOLECULAR METALLATION OF o-CARBORANYLPHOSPHINE-PALLADIUM(II) AND -PLATINUM(II) COMPLEXES

Preparation of trans-cbMCl2>-type complexes (Pcb=o-HCB10H10CCH2PPh2 M=Pd, Pt), which readily undergo intramolecular metallation through the B-H bonds of the carborane cage to form exocyclic compounds involving a bond system, is described.Both monomeric compounds, trans-cb>, and bridged complexes, such as , are formed, where (B-P) is intramolecular-metallated carborane phosphine.The bridging bond is readily cleaved under the action of various ligands (pyridine, PEt3, etc.) to form monomeric compounds.