37003-04-6

Basic information

• Product Name: tri(phenylethynyl)arsane
• Synonyms: tri(phenylethynyl)arsane
• CAS NO: 37003-04-6
• Molecular Weight: 378.305
• Mol File: 37003-04-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tri(phenylethynyl)arsane(CAS DataBase Reference)
• NIST Chemistry Reference: tri(phenylethynyl)arsane(37003-04-6)
• EPA Substance Registry System: tri(phenylethynyl)arsane(37003-04-6)

Safety Data

• Hazardous Substances Data: 37003-04-6(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 3126-13-4 Tri-n-propylphenylethinyl-stannan 
• 33440-88-9 silver phenylacetylide 
• 7784-34-1 arsenic trichloride 
• 6738-06-3 phenylethynylmagnesium bromide 

Downstream Products

• 132040-52-9 {((C₆H₅)CC)2As(Co(CO)2CCo(CO)3C(C₆H₅))}2 
• 132012-30-7 (PhCC)As{(η2-CCPh)Co2(CO)6}2 
• 132012-29-4 (PhCC)2As{(η2-CCPh)Co2(CO)6} 

Relevant articles and documents

Reaction of Tri(phenylethynyl)arsane and -stibane with Octacarbonyldicobalt; Crystal Structure of (Ph-CC)As2-CC-Ph)Co2(CO)6>2

The synthesis of tri(phenylethynyl)arsane (1) and -stibane (7) is discussed.Octacarbonyldicobalt reacts selectively with 1 or 7 to yield the η2-side-on co-ordinated phenylethynyl complexes (Ph-CC)nE2-CC-Ph)Co2(CO)6>3-n (E = As: n = 2: 3, n = 1: 4, n = 0: 5; E = Sb: n = 2: 8; n = 1: 9; n = 0: 10), which contain sterically hindered carbon-cobalt tetrahedrane cluster units. 3 gives upon heating 2-CC-Ph)Co2(CO)5>>2 (6) a compound containing a six-membered Co2As2C2 ring.All new compounds have been characterized by analytical and spectroscopic data (IR, 1H, 13C NMR), and (Ph-CC)As2-CC-Ph)Co2(CO)6>2 (4) by X-ray analysis.