37021-41-3Relevant academic research and scientific papers
OBSERVATION OF A COMPETITIVE PATH IN THE NUCLEOPHILIC ADDITION OF FLUOROOLEFINS: THE BROMOPHILIC REACTION OF THE ADDUCT CARBANOIN INTERMEDIATE
Jiang, Xi-Kui,Ji, Guo-Znen,Shi,Yi-Qun
, p. 405 - 418 (1987)
In addition to the hydro-alkoxy-addition products ROCF2CFBrH (4), and olefin products ROCF=CFBr (5), a new type of product, i.e., the alkoxy-bromo-addition products ROCF2CFBr2 (6) have been obtained in the reactions of bromotrifluoro-ethene (3) with different alkoxides (RO- = t-BuO=, i-PrO-, EtO- and MeO-).These products (6) are formed from a competitive path involving bromophilic reactions of the intermediate adduct carbanions (8).Radicals have been shown to be unlikely intermediates of this competitive reaction path.
