Journal of Fluorine Chemistry p. 405 - 418 (1987)
Update date:2022-08-04
Topics:
Jiang, Xi-Kui
Ji, Guo-Znen
Shi,Yi-Qun
In addition to the hydro-alkoxy-addition products ROCF2CFBrH (4), and olefin products ROCF=CFBr (5), a new type of product, i.e., the alkoxy-bromo-addition products ROCF2CFBr2 (6) have been obtained in the reactions of bromotrifluoro-ethene (3) with different alkoxides (RO- = t-BuO=, i-PrO-, EtO- and MeO-).These products (6) are formed from a competitive path involving bromophilic reactions of the intermediate adduct carbanions (8).Radicals have been shown to be unlikely intermediates of this competitive reaction path.
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Doi:10.1007/BF00771553
()Doi:10.1021/acs.orglett.7b03741
(2018)Doi:10.1016/S0040-4039(02)02110-X
(2002)Doi:10.1007/BF00924780
(1961)Doi:10.1021/jo00943a042
(1973)Doi:10.1016/j.jcat.2005.04.012
(2005)
