370556-45-9

Basic information

• Product Name: N-Nitro-N-methylpentafluoroaniline
• Synonyms: N-Nitro-N-methylpentafluoroaniline
• CAS NO: 370556-45-9
• Molecular Weight: 242.105
• Mol File: 370556-45-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-Nitro-N-methylpentafluoroaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Nitro-N-methylpentafluoroaniline(370556-45-9)
• EPA Substance Registry System: N-Nitro-N-methylpentafluoroaniline(370556-45-9)

Safety Data

• Hazardous Substances Data: 370556-45-9(Hazardous Substances Data)

Upstream product

• 1201-02-1 2,3,4,5,6-pentafluoro-N-methylaniline 
• 1801-14-5 1-(N,N-dimethylamine)pentafluorobenzene 
• 445026-75-5 N-Nitroso-N-methylpentafluoroaniline 

Downstream Products

• 527-21-9 2,3,5,6-tetrafluoro-1,4-benzoquinone 
• 445026-75-5 N-Nitroso-N-methylpentafluoroaniline 

Relevant articles and documents

Interaction of N,N-dimethylperfluoroarylamines with nitric and nitrous acids

N,N-Dimethylpentafluoroaniline enters easily into reactions with a mixture of nitric and sulphuric acids or nitric acid with conversion of the side chain. In the reactions with mixtures of HNO3 and H2SO4, the formation of N-nitroso-N-methyl and N-nitro-N-methylpentafluoroanilines is observed. The ratio of these products was found to depend on the ratio of the acids: the formation of N-nitro-N-methylpentafluoroaniline increases with the quantity of sulphuric acid; N-nitroso-N-methylpentafluoroaniline is obtained when only nitric acid is employed. N,N-Dimethylperfluoro-p-toluidine, N,N-dimethylperfluoro-2,4-xylidine, N,N-dimethylperfluoro-5-aminoindane undergo similar transformations. N-Nitroso derivatives were converted by a mixture of HNO3 and H2SO4, HNO3 or NO2BF4 into the corresponding N-nitro derivatives. Formation of the corresponding N-nitroso-N-methyl derivatives occurs when N,N-dimethylpentafluoroaniline, N,N-dimethylperfluoro-p-toluidine are treated with HNO2.