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CAS

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370568-15-3

(1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 370568-15-3 Structure

  • Basic information

    1. Product Name: (1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane
    2. Synonyms: (1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane
    3. CAS NO:370568-15-3
    4. Molecular Formula:
    5. Molecular Weight: 365.518
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 370568-15-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane(370568-15-3)
    11. EPA Substance Registry System: (1R,2R)-7,7-dimethyl-1-methylsulfanylmethyl-2-(4-nitrothiobenzoyl)bicyclo[2.2.1]heptane(370568-15-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 370568-15-3(Hazardous Substances Data)

370568-15-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 370568-15-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,7,0,5,6 and 8 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 370568-15:
(8*3)+(7*7)+(6*0)+(5*5)+(4*6)+(3*8)+(2*1)+(1*5)=153
153 % 10 = 3
So 370568-15-3 is a valid CAS Registry Number.

370568-15-3Upstream product

370568-15-3Relevant articles and documents

Asymmetric Pauson-Khand reactions using camphor-derived chelating thiols as chiral controllers

Marchueta,Montenegro,Panov,Poch,Verdaguer,Moyano,Pericas,Riera

, p. 6400 - 6409 (2001)

A convenient procedure for the preparation of enantiopure 10-(R-thio)-2-exo-bornanethiols from (1S)-camphor-10-thiol has been developed. The ethynyl derivatives of these thiols gave excellent diastereoselectivities (up to 98:2) in Pauson-Khand reactions with norbornene and norbornadiene through the intermediacy of a chelated dicobalt pentacarbonyl complex. Thermal reaction conditions starting from the preformed chelated complex gave better results than N-oxide-promoted runs with in situ generation of the chelated intermediate. The corresponding adducts have been elaborated through a protocol consisting of conjugate addition, samarium iodide-promoted cleavage of the chiral auxiliary, and retro-Diels-Alder reaction to afford 4-substituted 2-cyclopentenones in high enantiomeric purity.

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