37112-08-6Relevant articles and documents
Substituent Effects on the CC Bond Strength, 17. - Formation and Stability of α-Carbamoylbenzyl Radicals
Zueffle, Stephan,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 877 - 880 (2007/10/02)
Products and kinetics of the homolytic thermolyses reactions of the three tertiary amides 6a-c of 2,3,3-triphenylpropanoic acid were studied in solution.The steric effects on the C-C bond homolysis processes were evaluated from MM2 calculations.Taking this into account, we deduced radical stabilization enthalpies RSE for the α-carbamoylbenzyl radicals 3a-c from the activation enthalpies ΔH(excit.) . - Key Words: Bond cleavage, C-C kinetics of / Radicals, stability of