37155-05-8Relevant academic research and scientific papers
Construction of N-Alkyl- and N-Arylaziridines from Unprotected Amines via C-H Oxidative Amination Strategy
Yu, Yang,Li, Meijuan,Zhang, Yong,Liu, Yonghai,Shi, Lei,Wang, Wei,Li, Hao
, p. 904 - 907 (2019)
A copper-promoted intramolecular C-H oxidative amination reaction between secondary amine (N-H) and C(sp3)-H at the benzylic position of azaarenes or α-position of ketones for the synthesis of aziridine derivatives has been developed. Moreover,
I2-Promoted Intramolecular Oxidative Cyclization of Butenyl Anilines: A Facile Route to Benzo[b]azepines
An, Zhenyu,Ren, Yi,Liu, Yafeng,Yan, Rulong
, p. 2614 - 2617 (2021/08/06)
A metal-free approach for the synthesis of seven-membered N-heterocycles has been developed by the I2-promoted intramolecular cross-coupling/annulation of butenyl anilines. This cyclization reaction involves C?H activation and C?C bond formation and exhibits good functional group tolerance. A series of benzo[b]azepine derivatives are obtained in moderate to good yields.
