37191-17-6 Usage
Description
Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is a complex chemical compound that features a central iron atom coordinated with four meso-tetrakis(4-methoxyphenyl)porphine ligands. The iron atom is connected to an oxygen atom through a μ-oxo bridge, creating a unique structure with potential applications in various fields.
Uses
Used in Catalysis:
Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer serves as a catalyst in various chemical reactions due to its ability to facilitate and speed up processes without being consumed in the reaction itself.
Used in Biomedical Science:
In the biomedical field, Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is utilized for its capacity to interact with biological molecules, making it a valuable tool in research and development.
Used in Drug Delivery:
Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is employed as a component in drug delivery systems, where it can enhance the efficiency and targeting of therapeutic agents to specific areas within the body.
Used in Imaging:
Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is used in imaging techniques to improve the visualization of biological structures and processes, aiding in diagnostics and research.
Used in Photodynamic Therapy:
It plays a role in photodynamic therapy, where it can be activated by light to produce a therapeutic effect, particularly useful in the treatment of certain diseases and conditions.
Used in Sensor Technology:
Due to its unique electronic and optical properties, Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is used in the development of sensors for detecting various substances.
Used in Optoelectronic Devices:
Its electronic and optical characteristics also make it a promising material for use in optoelectronic devices, which can have applications in various high-tech industries.
Used in Synthesis of Porphyrin-based Materials:
As an important intermediate, Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer is utilized in the synthesis of a variety of porphyrin-based materials, contributing to the advancement of new technologies and products.
Check Digit Verification of cas no
The CAS Registry Mumber 37191-17-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,1,9 and 1 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 37191-17:
(7*3)+(6*7)+(5*1)+(4*9)+(3*1)+(2*1)+(1*7)=116
116 % 10 = 6
So 37191-17-6 is a valid CAS Registry Number.
37191-17-6Relevant articles and documents
Identification of High-Valent Fluoroiron Porphyrin Intermediates Associated with the Electrocatalytic Functionalization of Hydrocarbons
Hickman, David L.,Nanthakumar, Alaganandan,Goff, Harold M.
, p. 6384 - 6390 (2007/10/02)
The difluoroiron(III) tetraphenylporphyrin complex undergoes a one-electron oxidation at 0.68 V (SCE) in contrast with values of 1.1 V measured for the monofluoroiron(III) porphyrin and the other five-coordinate iron(III) porphyrin complexes.Cyclic voltammetric oxidation of the difluoroiron(III) species in dichloromethane solution is quasi-reversible as a consequence of an EC mechanism.Reversible waves are favored at high scan rates and lower temperatures.Increased water content serves to make the oxidative cyclic voltammetric process irreversible presumably due to a disproportionation process.In the presence of added olefin substrates, this EC process permits efficient electrocatalytic oxidation to the epoxide, allylic alcohol, and enone.Tertiary carbon units are converted to the corresponding alcohol.Utilization of fluoride ion permits generation and low-temperature spectroscopic identification of a highly oxidized iron porphyrin species.The high-valent complex is produced at -78 deg C through addition of m-chloroperbenzoic acid to monofluoroiron(III) tetraarylporphyrins or by fluoride ion promoted disproportionation of the dication radical μ-oxo dimeric iron(III) porphyrin derivative.The oxidized iron porphyrin species is competent to effect olefin epoxidation at -78 deg C.Low-temperature 1H and 2H NMR spectroscopies demonstrate the porphyrin ?-cation radical nature of the high-valent species, in that porphyrin phenyl resonances are drastically shifted in alternating upfield and downfield directions.The electron spin resonance spectrum is consistent with an S = 3/2 ground state, and the high-valent intermediate is assigned a tentative fluorooxoiron(IV) porphyrin ?-cation radical formulation.
