Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer

Base Information

• Chemical Name: Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer
• CAS No.: 37191-17-6
• Molecular Formula: C96H72Fe2N8O9
• Molecular Weight: 0
• Mol file: 37191-17-6.mol

Synonyms:Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer

Chemical Property of Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer

Chemical Property:

• PSA: 114.83000
• LogP: 12.87100

Purity/Quality:

98.5% ^*data from raw suppliers

μ-oxo-bis(meso-tetra-p-methoxyphenylporphyrin)iron(III) 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer

There total 3 articles about Iron(III)meso-tetrakis(4-methoxyphenyl)porphine-μ-oxodimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(C20H8N4(C6H4OCH3)4)FeCl (36995-20-7,333460-15-4) → (μ-oxo)bis[(meso-tetrakis(4-methoxyphenyl)porphinato)iron(III)] (37191-17-6)

Guidance literature:

With sodium hydroxide; In sodium hydroxide; dichloromethane; Fe-complex in CH2Cl2 stirred with aq. 2 N NaOH for 4 h; organic layer separated; dried over Na2SO4; evapd.; chromy.; concentrated; hexane added; filtered; evacuated for 2 h at ambient temp.; elem. anal.;

Reference yield:

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin + iron(II) acetate (1834-30-6,2140-52-5,3094-87-9) → {(p-OMeTPP)Fe}2O (37191-17-6)

Guidance literature:

With potassium hydroxide; acetic acid; In water; acetic acid; refluxing, diln. (water), extraction (benzene), addn. of aq. KOH, stirring (overnight); sepn. of benzene phase, washing (water), chromy. (benzene/chloroform), filtration, evapn., drying (vac., 80°C, 4 h); elem. anal.;

DOI:10.1016/0013-4686(86)80144-X

Reference yield:

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin + iron(II) chloride → {(p-OMeTPP)Fe}2O (37191-17-6)

Guidance literature:

In dichloromethane; water; N,N-dimethyl-formamide; 10-fold exess of FeCl2 added to a refluxing DMF soln. of p-OMeTPPH2 under a N2 atm. results an iron(III) porphyrin (recovered by the addn. of aq. NaCl soln. and not further characterized), which was equilibrated with an aq. NaOH soln. in CH2Cl2;; purifn. by silica gel chromatography followed by a basic alumina column (in CH2Cl2);;

DOI:10.1021/ja00227a019

upstream raw materials:

iron(II) acetate

(C₂₀H₈N₄(C₆H₄OCH₃)4)FeCl

Downstream raw materials:

(5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride

5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

[Na(kryptofix-222)][Fe(tetra-p-methoxyphenylporphyrinate)(SH)]*0.5C₆H₆