373393-06-7Relevant academic research and scientific papers
A direct and useful route to difluoroacylsilanes and difluoroacylstannanes and their potential for the generation of structurally diverse difluoroketones
Garayt, Maxime R,Percy, Jonathan M
, p. 6377 - 6380 (2001)
Allyl trifluoroethyl ethers 2a-2d were prepared; each underwent efficient dehydrofluorination/metallation and trapping to afford a range of difluoroenol silanes and stannanes which rearranged easily and efficiently to the acyl metals. Fluoride-mediated be
A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol
Audouard, Christophe,Garayt, Maxime R.,Kérourédan, Erwan,Percy, Jonathan M.,Yang, Hongli
, p. 611 - 623 (2007/10/03)
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitatio
