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3734-67-6

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3734-67-6 Usage

Chemical Properties

Dark red powder

Uses

Different sources of media describe the Uses of 3734-67-6 differently. You can refer to the following data:
1. Acid Red 1 is a synthetic red azo dye used as food additive. Studies have shown that Red Acid 1 is converted to toxic compound aniline and may ultimately interfere with blood haemoglobin.
2. A useful stain with color index of 18050.

Definition

ChEBI: An organic sodium salt that is the disodium salt of 5-acetamido-4-hydroxy-3-(phenyldiazenyl)naphthalene-2,7-disulfonic acid.

Preparation

aniline diazo, and 4-Acetamido-5-hydroxynaphthalene-2,7-disulfonic acid coupling.

Flammability and Explosibility

Nonflammable

Properties and Applications

colourful red blue light. Red powder. Soluble in water solution for big red, slightly soluble in ethanol and soluble fiber element, insoluble in other organic solvents. Meet strong sulfuric acid is blue light red, it will be diluted in a yellow after red; Meet nitric acid solution is orange turn orange; Meet strong hydrochloric acid generation red precipitation, dilute it dissolve. The aqueous solution of dyes and strong hydrochloric acid is product red; Add sodium hydroxide is orange brown. Copper ions in dyeing and dark blue colour and lustre to take; Iron ion in color with blue and light. Good levelness. Mainly used in strong acid medium in the wool dyeing and the piece dyed wool. Can be directly in the wool fabrics, polyamide fiber and fabric silk printing. Also can be used for leather dyeing, also can be used in the manufacture of color amylum, cosmetics, paper, soap and timber colorants, is used to make the ink. The Barium salt can be used in organic pigments. Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater Fading Stain Fading Stain Fading Stain ISO 5 3 5 4-5 1 4 2 1 AATCC 4 2 2 2 1 1 2 2

Standard

Light Fastness

Fading

Stain

ISO

5

AATCC

4

Purification Methods

Salt it out three times with sodium acetate, then repeatedly extract it with EtOH. See Solochrome Violet R in “Aromatic compounds”, Chapter 4. [McGrew & Schneider J Am Chem Soc 72 2547 1950.]

Check Digit Verification of cas no

The CAS Registry Mumber 3734-67-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,7,3 and 4 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 3734-67:
(6*3)+(5*7)+(4*3)+(3*4)+(2*6)+(1*7)=96
96 % 10 = 6
So 3734-67-6 is a valid CAS Registry Number.
InChI:InChI=1/C18H15N3O8S2.2Na/c1-10(22)19-14-9-13(30(24,25)26)7-11-8-15(31(27,28)29)17(18(23)16(11)14)21-20-12-5-3-2-4-6-12;;/h2-9,20H,1H3,(H,19,22)(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2/b21-17-;;

3734-67-6 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (A0585)  Acid Red 1  

  • 3734-67-6

  • 25g

  • 310.00CNY

  • Detail
  • TCI America

  • (A0585)  Acid Red 1  

  • 3734-67-6

  • 100g

  • 870.00CNY

  • Detail
  • TCI America

  • (A0585)  Acid Red 1  

  • 3734-67-6

  • 500g

  • 2,850.00CNY

  • Detail
  • Sigma-Aldrich

  • (40462)  Red 2G  analytical standard

  • 3734-67-6

  • 40462-25MG

  • 1,559.61CNY

  • Detail

3734-67-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name azophloxine

1.2 Other means of identification

Product number -
Other names Acid Red 1,Amido Naphthol Red G,Azophloxine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3734-67-6 SDS

3734-67-6Synthetic route

C12H9NO8S2(2-)*2Na(1+)

C12H9NO8S2(2-)*2Na(1+)

aniline
62-53-3

aniline

azophloxine
3734-67-6

azophloxine

Conditions
ConditionsYield
Stage #1: aniline With hydrogenchloride In water; N,N-dimethyl-formamide at 25℃;
Stage #2: With sodium nitrite In water; N,N-dimethyl-formamide
Stage #3: C12H9NO8S2(2-)*2Na(1+) In water; N,N-dimethyl-formamide at 25℃; for 0.00888889h;
98.2%
azophloxine
3734-67-6

azophloxine

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

Conditions
ConditionsYield
With TiO2; NaF; formic acid In water Kinetics; Irradiation (UV/VIS); aq. NaF added to TiO2; aq. suspn. of Acid Red 1 on fluorinated TiO2 in presence of formic acid irradiated (315-400 nm) at 35°C underatmospheric conditions; monitored by spectrophotometrically and by fluorimetric analysis;
titanium(IV) oxide In water Kinetics; Irradiation (UV/VIS); aq. suspn. of Acid Red 1 contg. TiO2 irradiated (315-400 nm) at 35°C under atmospheric conditions; monitored by spectrophotometrically and by fluorimetric analysis;
With 2-propanol; titanium(IV) oxide In water Kinetics; Irradiation (UV/VIS); aq. suspn. of Acid Red 1 contg. TiO2 and 2-propanol irradiated (315-400 nm) at 35°C underatmospheric conditions; monitored by spectrophotometrically and by fluorimetric analysis;
azophloxine
3734-67-6

azophloxine

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
With dihydrogen peroxide at 70℃; pH=6.7; Kinetics; Reagent/catalyst; pH-value; Temperature;
azophloxine
3734-67-6

azophloxine

A

carbon dioxide
124-38-9

carbon dioxide

B

Ammonium

Ammonium

C

Nitrate

Nitrate

D

Sulfate
14808-79-8

Sulfate

Conditions
ConditionsYield
With ferrous(II) sulfate heptahydrate; sulfuric acid; water; oxygen; sodium sulfate at 35℃; pH=3.0; Kinetics; Mechanism; Reagent/catalyst; Electrochemical reaction; UV-irradiation;
azophloxine
3734-67-6

azophloxine

A

C10H9NO7S

C10H9NO7S

B

C10H9NO8S

C10H9NO8S

C

C9H9NO7S

C9H9NO7S

D

C9H9NO6S

C9H9NO6S

Conditions
ConditionsYield
With CdS99.98Sm0.02 for 1.5h; pH=6; Kinetics; Reagent/catalyst; Irradiation;
azophloxine
3734-67-6

azophloxine

A

aniline
62-53-3

aniline

B

benzene-1,2-dicarboxylic acid
88-99-3

benzene-1,2-dicarboxylic acid

Conditions
ConditionsYield
With dihydrogen peroxide In water at 60℃; for 12h; pH=2; Kinetics; Catalytic behavior; Reagent/catalyst; pH-value; Temperature;

3734-67-6Upstream product

3734-67-6Relevant articles and documents

A method for continuously preparing azo dye in micro-reactors

-

Paragraph 0078-0084, (2018/04/01)

The invention discloses a method for continuously preparing azo dye in micro-reactors in the field of dye synthesis. The azo dye is prepared by firstly subjecting a sodium nitrite solution, an aromatic primary amine and an inorganic acid to a diazotization reaction at room temperature in a first micro-reactor to generate an aromatic primary amine diazonium salt; and then subjecting the aromatic primary amine diazonium salt and a coupling component to a coupling reaction in a second micro-reactor to generate the azo dye. Continuous preparation of the azo dye is achieved by utilizing the micro-reactors, a process is simple, a reaction period is short, and a reaction process can be easily monitored and controlled. Addition of an excessive amount of the sodium nitrite and the coupling agent to increase the reaction speed is not required so that raw materials are saved and the method is environmentally friendly. Reaction liquid in the micro-reactors achieves high-speed collision mixing, a uniform reaction environment is formed immediately, the reaction efficiency is high, and the yield and quality of a reaction product are greatly improved.

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