374551-13-0

Basic information

• Product Name: Boronic acid, [2-(chloromethyl)phenyl]-
• CAS NO: 374551-13-0
• Molecular Formula: C7H8BClO2
• Molecular Weight: 170.403
• Mol File: 374551-13-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 147 °C (diethyl ether)
• CAS DataBase Reference: Boronic acid, [2-(chloromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Boronic acid, [2-(chloromethyl)phenyl]-(374551-13-0)
• EPA Substance Registry System: Boronic acid, [2-(chloromethyl)phenyl]-(374551-13-0)

Safety Data

• Hazardous Substances Data: 374551-13-0(Hazardous Substances Data)

Upstream product

• 59473-45-9 2-(chloromethyl)iodobenzene 

Downstream Products

• 1040264-41-2 3-butyl-2-(4-trifluoromethylphenyl)-1H-indene 
• 1040264-42-3 3-butyl-2-(2-methylphenyl)-1H-indene 
• 1040264-47-8 3-(2-chloromethylphenyl)propanal 
• 5324-00-5 2,3-diphenyl-1H-indene 
• 1040264-45-6 4-(2-chloromethylphenyl)butan-2-one 
• 1040264-40-1 3-butyl-2-(4-methoxyphenyl)-1H-indene 
• 229637-58-5 3-butyl-2-phenyl-1H-indene 
• 1040264-39-8 2,3-dibutyl-1H-indene 
• 10425-96-4 3-methyl-2-phenyl-1H-indene 
• 374551-14-1 2-(chloromethyl)phenyllead triacetate 

Relevant articles and documents

Rh(I)-catalyzed reaction of 2-(chloromethyl)phenylboronic acids and alkynes leading to indenes

(Chemical Equation Presented) The reaction of 2-(chloromethyl)phenylboronic acid (1) with alkynes in the presence of a Rh(I) complex gave indene derivatives in high yields. The regioselectivity depends on the steric nature of the substituent on the alkynes. A bulky group favors the α-position of indenes.

Aryllead triacetates in the synthesis of oxaphenanthrene derivatives

Ortho-Halomethylphenyllead triacetates (halo = bromine or chlorine) react with phenols in the presence of triethylamine and a pyridine derivative to afford modest to good yields of dibenzo[b,d]-6H-pyrans.