37493-70-2

Basic information

• Product Name: 5-UNDECANOL
• Synonyms: 5-UNDECANOL;n-Butyl n-hexyl carbinol;undecan-5-ol;5-Hendecanol;Butylhexylcarbinol;Undecane-5-ol
• CAS NO: 37493-70-2
• Molecular Formula: C₁₁H₂₄O
• Molecular Weight: 172.31
• EINECS: 253-529-6
• Mol File: 37493-70-2.mol
• Article Data: 9

Chemical Properties

• Melting Point: -4°C
• Boiling Point: 139-140°C 17mm
• Flash Point: 139-140°C/17mm
• Appearance: /
• Density: 0,83 g/cm3
• Vapor Pressure: 0.0132mmHg at 25°C
• Refractive Index: 1.4362
• PKA: 15.44±0.20(Predicted)
• BRN: 1698382
• CAS DataBase Reference: 5-UNDECANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 5-UNDECANOL(37493-70-2)
• EPA Substance Registry System: 5-UNDECANOL(37493-70-2)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 37493-70-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 27, p. 4445, 1986 DOI: 10.1016/S0040-4039(00)84974-6

InChI:InChI=1/C11H24O/c1-3-5-7-8-10-11(12)9-6-4-2/h11-12H,3-10H2,1-2H3

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 111-71-7 heptanal 
• 33083-83-9 undecan-5-one 
• 542-69-8 1-iodo-butane 
• 101820-17-1 C₄H₉Cl₃Hf 
• 96-22-0 pentan-3-one 
• 101820-18-2 C₄H₉Cl₃Zr 
• 109-72-8 n-butyllithium 
• 34009-04-6 phenyl pentyl sulfone 
• 82941-75-1 C₄H₉Cl₄Ta 
• 82941-71-7 C₄H₉Cl₄Nb 
• 105486-12-2 n-butylmanganese (II) bromide 
• 88626-90-8 BuMnCl 
• 66858-75-1 (1-Iodo-heptyloxy)-trimethyl-silane 

Downstream Products

• 33083-83-9 undecan-5-one 

Relevant articles and documents

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The evaluation of dicyclopentadienylsamarium as a reagent in organic synthesis

SmCp2, which is easily prepared from SmI2, has been screened as a reducing agent for organic chemistry. In particular, SmCp2 promotes the pseudo-Barbier reaction between carbonyl compounds (aldehydes and ketones) and aliphatic or allylic halides more efficiently than does SmI2.

ALDEHYDSELEKTIVITAET VON ALKYLHAFNIUM-KOMPLEXEN IN ALDEHYD-KETONKONKURRENZVERSUCHEN; VERGLEICH ZU ZIRKONIUM- UND TITAN-ANALOGEN KOMPLEXEN SOWIE THEORETISCHE DEUTUNG

Cl3Hf-Me, in contrast to MeLi is not able to attack an ester or a nitrile group and fails to discriminate in competition experiments between heptanal and diethylketone.To the contrary, Cl3Hf-Bu and (EtO)3Hf-Me are highly aldehyde-selective.An explanation of these findings in comparison with alkylzirconium and alkyltitanium complexes is given.