375385-32-3Relevant academic research and scientific papers
Development of a Friedel-Crafts triflation
Grundl, Marc A.,Kaster, Anne,Beaulieu, Ellen D.,Trauner, Dirk
, p. 5429 - 5432 (2007/10/03)
The development of a new variant of the Friedel-Crafts reaction that yields 3-aryl enol triflates is described. The reaction is practical, is atom-economical, and works well with electron-rich arene substrates.
Intramolecular conjugate addition of alkenyl and aryl functions to enones initiated by lithium-iodine exchange
Piers, Edward,Harrison, Cristian L.,Zetina-Rocha, Carlos
, p. 3245 - 3247 (2007/10/03)
Equation presented Treatment of each of the substrates 20-26, 29, and 46-48 with t-BuLi in THF, in the presence of HMPA and TMSCI, provides good-to-excellent yields of the intramolecular conjugate addition products 30-36, 37, and 49-51, respectively.
