37559-04-9

Basic information

• Product Name: 5-methoxy-[1,1'-biphenyl]-2,2'-dicarbaldehyde
• CAS NO: 37559-04-9
• Molecular Weight: 240.258
• Mol File: 37559-04-9.mol

Chemical Properties

• CAS DataBase Reference: 5-methoxy-[1,1'-biphenyl]-2,2'-dicarbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methoxy-[1,1'-biphenyl]-2,2'-dicarbaldehyde(37559-04-9)
• EPA Substance Registry System: 5-methoxy-[1,1'-biphenyl]-2,2'-dicarbaldehyde(37559-04-9)

Safety Data

• Hazardous Substances Data: 37559-04-9(Hazardous Substances Data)

Upstream product

• 43192-31-0 2-bromo-4-methoxybenzaldehyde 
• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 1392144-08-9 C₂₉H₂₈N₄O₅S₂ 

Relevant articles and documents

A modified Cu(0)-Cu(I)-mediated Caryl-CarylUllmann coupling for the synthesis of biaryls

A novel Cu(0)-Cu(I)-mediated Caryl-CarylUllmann coupling has been successfully developed. The use of Cu(I) salts allowed the reactions to proceed under relatively mild conditions (65?°C in DMSO for 15–72?h). The developed method was compatible with a relatively wide range of functional groups simultaneously present on the aromatic ring of different electronic nature. The aryl halides with an electron-withdrawing group ortho to the halide or an electron-donating group meta or para to the halide furnished the corresponding products in good to excellent yields (up to 98%).