43192-31-0

Basic information

• Product Name: 2-BROMO-4-METHOXYBENZALDEHYDE
• Synonyms: B90014;2-Bromo-p-anisaldehyde;3-Bromo-4-formylanisole, 2-Bromo-p-anisaldehyde;Benzaldehyde, 2-broMo-4-Methoxy-;2-BroMo-4-Methoxybenzaldehyde, 97+%;3-Bromo-4-formylanisole
• CAS NO: 43192-31-0
• Molecular Formula: C₈H₇BrO₂
• Molecular Weight: 215.045
• Mol File: 43192-31-0.mol
• Article Data: 15

Chemical Properties

• Melting Point: 68-69℃
• Boiling Point: 284℃
• Flash Point: 126℃
• Appearance: /Solid
• Density: 1.522
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 2-BROMO-4-METHOXYBENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BROMO-4-METHOXYBENZALDEHYDE(43192-31-0)
• EPA Substance Registry System: 2-BROMO-4-METHOXYBENZALDEHYDE(43192-31-0)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-50
• Safety Statements: 61
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 43192-31-0(Hazardous Substances Data)

Usage

Chemical Properties

White solid

InChI:InChI=1S/C8H7BrO2/c1-11-7-3-2-6(5-10)8(9)4-7/h2-5H,1H3

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 99177-37-4 1-(2-bromo-4-methoxyphenyl)-N,N-dimethylmethanamine 
• 59142-68-6 2-bromo-4-fluorobenzaldehyde 
• 124-41-4 sodium methylate 
• 2398-37-0 3-methoxyphenyl bromide 
• 75-36-5 acetyl chloride 
• 4885-02-3 Dichloromethyl methyl ether 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 36942-56-0 3-bromo-4-methylanisole 

Downstream Products

• 102878-93-3 2-bromo-4-methoxy-trans-cinnamic acid 
• 362057-78-1 [(E)-2-(2-Bromo-4-methoxy-phenyl)-1-(3,4,5-trimethoxy-phenyl)-vinyl]-(4-methoxy-benzyl)-methyl-amine 
• 163190-79-2 (2-bromo-4-methoxyphenyl)methanol 
• 925452-26-2 C₁₁H₁₄BrNO₃S 
• 873843-72-2 (R)-4-(2-bromo-4-methoxybenzyl)-3-methyl-1,2,3-oxathiazolidine 2,2-dioxide 
• 873843-74-4 (R)-3-(2-bromo-4-methoxyphenyl)-2-tert-butoxycarbonylaminopropionic acid methyl ester 
• 873843-75-5 [(R)-2-(2-bromo-4-methoxyphenyl)-1-hydroxymethylethyl]-carbamic acid tert-butyl ester 
• 1026299-19-3 C₁₁H₁₂BrNO₃ 
• 1025995-08-7 (R)-4-(2-bromo-4-methoxybenzyl)-3-methyloxazolidin-2-one 
• 873843-76-6 (R)-3-(2-bromo-4-methoxyphenyl)-2-(methylamino)propan-1-ol 
• 557056-03-8 7-(2-bromo-4-methoxyphenyl)heptanenitrile 
• 557056-04-9 4-[2-(6-cyanohexyl)-5-methoxyphenyl]piperazine-1-carboxylic acid tert-butyl ester 
• 557056-05-0 4-{2-[7-(bis-tert-butoxycarbonylmethyl-amino)heptyl]-5-methoxyphenyl}piperazine-1-carboxylic acid tert-butyl ester 
• 1046763-87-4 C₁₃H₁₆BrNO₃ 

Relevant articles and documents

Visible-Light-Mediated α-Oxygenation of 3-(N,N-Dimethylaminomethyl)-Indoles to Aldehydes

The visible-light-mediated oxygenation of 3-N,N-(dimethylaminomethyl)-indoles bearing various substituents afforded a series of 3-carbaindole derivatives. Herein we describe the reaction scope, a plausible mechanism and a practical application of this transformation in the formal synthesis of (–)-vincorine is described as well.

Cyclotrimerization of unsymmetrically bromo-substituted diynes: Toward the synthesis of potential selective inhibitors of tyrosine kinase 2

A study on transition metal catalyzed alkyne cyclotrimerization of unsymmetrically bromo-substituted diynes with ethynyltrimethylsilane was carried out to prepare bicyclic bromobenzene key intermediates for the total synthesis of five potential tyrosine k

Asymmetric total syntheses of (-)-variabilin and (-)-glycinol

Total syntheses of (-)-variabilin and (-)-glycinol have been accomplished, using the catalytic, asymmetric "interrupted" Feist-Benary reaction (IFB) as the key transformation to introduce both stereogenic centers. A monoquinidine pyrimidinyl ether catalyst affords the IFB products in over 90% ee in both cases. Other key steps include an intramolecular Buchwald-Hartwig coupling and a nickel-catalyzed aryl tosylate reduction.