3756-36-3Relevant academic research and scientific papers
Efficient and highly aldehyde selective wacker oxidation
Teo, Peili,Wickens, Zachary K.,Dong, Guangbin,Grubbs, Robert H.
supporting information; experimental part, p. 3237 - 3239 (2012/08/27)
A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl2(MeCN)2, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates.
Diazo reactions with unsaturated compounds: V.1 reaction of phenyl vinyl ether with arenediazonium chlorides
Naidan
, p. 1600 - 1602 (2007/10/03)
Phenyl vinyl ether reacts with arenediazonium chlorides in aqueous acetone at pH 3-4 in the presence of a catalytic amount of copper(II) chloride to give arylacetaldehydes and small amounts 1-aryl-2-phenoxyethenes. No reaction occurs between the same reactants in the presence of sulfur(IV) oxide. 2000 MAIK "Nauka/Interperiodica".
