37567-79-6 Usage
Uses
Used in Pharmaceutical Research:
1-(2-BROMOETHYL)-2,4-DIMETHOXYBENZENE is used as a building block for the synthesis of various pharmaceutical drugs. Its unique structure allows for the creation of a range of compounds with different therapeutic properties, contributing to the development of novel medications.
Used in Organic Synthesis:
In the field of organic synthesis, 1-(2-BROMOETHYL)-2,4-DIMETHOXYBENZENE serves as an intermediate, facilitating the production of a diverse array of organic compounds. Its versatility in chemical reactions makes it a valuable component in the synthesis of specialty chemicals and materials.
Used in Materials Science:
1-(2-BROMOETHYL)-2,4-DIMETHOXYBENZENE is used as a component in the development of new materials with specific properties. Its incorporation into material formulations can lead to advancements in material science, potentially enhancing the performance of existing materials or creating new ones with unique characteristics.
Used in Organic Electronics:
This chemical compound is also utilized in the field of organic electronics, where it may contribute to the development of novel electronic devices or components. Its electronic properties and structural features make it a candidate for use in the design and fabrication of organic electronic systems.
Check Digit Verification of cas no
The CAS Registry Mumber 37567-79-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,5,6 and 7 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 37567-79:
(7*3)+(6*7)+(5*5)+(4*6)+(3*7)+(2*7)+(1*9)=156
156 % 10 = 6
So 37567-79-6 is a valid CAS Registry Number.
37567-79-6Relevant academic research and scientific papers
Synthetic access to optically active isoflavans by using allylic substitution
Takashima, Yuji,Kaneko, Yuki,Kobayashi, Yuichi
experimental part, p. 197 - 207 (2010/03/03)
A general approach to the (S)- and (R)-isoflavans was invented, and efficiency of the method was demonstrated by the synthesis of (S)-equol ((S)-3), (R)-sativan ((R)-4), and (R)-vestitol ((R)-5). The key step is the allylic substitution of (S)-6a (Ar1=2,4-(MeO)2C6H3) and (R)-6b (Ar1=2,4-(BnO)2C6H3) with copper reagents derived from CuBr·Me2S and Ar2-MgBr (7a, Ar2=4-MeOC6H4; 7b, 2,4-(MeO)2C6H3; 7c, 2-MOMO-4-MeOC6H3), furnishing anti SN2′ products (R)-8a and (S)-8b,c with 93-97% chirality transfer in 60-75% yields. The olefinic part of the products was oxidatively cleaved and the Me and Bn groups on the Ar1 moieties was then removed. Finally, phenol bromide 9a and phenol alcohols 9b,c underwent cyclization with K2CO3 and the Mitsunobu reagent to afford (S)-3 and (R)-4 and -5, respectively.
New synthetic route to (S)-(-)-equol through allylic substitution
Takashima, Yuji,Kobayashi, Yuichi
, p. 5156 - 5158 (2008/12/20)
Allylic substitution of allylic picolinate 5 with a copper reagent derived from p-MeOC6H4MgBr (6) and CuBr·Me2S produced the anti SN2′ product 7 with high regioselectivity and efficient chirality transfer. Oxidative cleavage of the olefinic function to the alcohol followed by bromination afforded bromide 16, which upon demethylation and intramolecular ether ring formation furnished (S)-(-)-equol (3).
