37609-31-7Relevant articles and documents
SPIRO KETONE SYNTHESIS VIA LITHIUM-IODINE EXCHANGE OF α-(ω-IODOALKYL) ESTERS
Does, T. van der,Klumpp, G. W.,Schakel, M.
, p. 519 - 520 (2007/10/02)
The title reaction (2 eq. of t-BuLi, -100 deg C) provides a new route to five- and six-membered ring ketones and has permitted the synthesis of two spiro ketones that were inaccessible by conventional methods.
The chemistry of small-ring compounds. Part 47. Small-ring interference in the ozonolysis of cyclopropylidenecycloalkanes
Heuvel, C. J. M. van den,Hofland, A.,Velzen, J. C. van,Steinberg, H.,Boer, Th. J. de
, p. 233 - 240 (2007/10/02)
Ozonolysis of olefins Ia-c containing a cyclpropylidene group, does not follow the classical Criegee mechanism but gives the anomalous products IIa-c, IIIa-c, IVa-c, and Va-c, as outlined in Scheme 2.None of these oxidation products contains the cycloprop
Cyclopropylidenecyclanes Oxydation par l'acide peroxycarboximidique
Bertrand, Marcel,Meou, Alain,Tubul, Arlette
, p. 3691 - 3694 (2007/10/02)
The title reaction gives a mixture of four compounds .A 2-cyclohexyllideneoxetane is invoked as intermediary to account for the unusual lactone formation.
