376353-55-8

Upstream product

• 106-38-7 para-bromotoluene 
• 121156-22-7 (+)-(R,R)-cis-carveolbenzoate 
• 119905-76-9 (1S,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl benzoate 
• 18412-57-2 p-tolyltriethoxysilane 

Relevant academic research and scientific papers

Efficient palladium-catalyzed nucleophilic addition of triorganoindium reagents to carbocyclic derivatives

Palladium (0)-catalyzed allylic substitution reactions employing triorganoindium reagents have been investigated. In situ generated vinyl- and arylindiums react with substituted and unsubstituted cyclohex-2-enyl esters in the presence of 1-3 mol % Pd2(dba)3 to produce vinyl- or arylcyclohexenes in moderate to excellent yields. The stereoselectivity of this process was also examined, and evidence is presented that the reaction proceeds with inversion of stereochemical configuration.

Palladium-catalyzed arylation of allylic benzoates using hypervalent siloxane derivatives

Palladium-catalyzed cross-coupling of hypervalent arylsiloxane derivatives proceeded in good to excellent yields with allylic benzoates. Arylation occurred with complete inversion of configuration. The scope and limitations of this reaction, an alternative to the Stille coupling, is summarized.